In a new publication in ACS Photonics, we show that optical spin orientations can be locked to intracavity propagation directions when a seed of planar (2D) chirality is present inside the cavity. This seed is given by inserting between the two metallic mirrors of a Fabry–Perot cavity a layer of polystyrene made 2D chiral under torsional shear stress. This planar chirality gives rise to an extrinsic source of three-dimensional chirality under oblique illumination that endows the cavities with enantiomorphic signatures measured experimentally and simulated with excellent agreement. The simplicity of this scheme is particularly promising in the context of chiral cavity QED and polaritonic asymmetric chemistry, driven by chiral polaritonic states.

Another paper, resulting from the collaboration between our group and Institute of Electro-Optical Engineering from National Taiwan Normal University, has been published in Nano Letters. Strong coupling provides a powerful way to modify the nonlinear optical properties of materials but the coupling strength is restricted by a weak-field confinement in cavities, which limits the enhancement of the optical nonlinearity. Here, we investigate a strong coupling between Mie resonant modes of high-index dielectric nanocavities and an epsilon-near-zero mode of an ultrathin indium tin oxide film and obtain an anticrossing splitting of 220 meV. In addition, static nonlinear optical measurements reveal a large enhancement in the intensity-independent effective optical nonlinear coefficients, reaching more than 3 orders of magnitude at the coupled resonance.

Just before he went back to India, the paper written by Sandeep Kulangara as first author has been accepted in Journal of Physical Chemistry Letters. The effects of cooperative vibrational strong coupling on the aggregation of two structural isomers of phenyleneethynylene was investigated and showed to lead to two different self-assembled structures, spheres and flakes, having distinct optical properties. These results confirm that VSC can be used to drive molecular assemblies and thereby provide a new tool for supramolecular chemistry.

In addition, Cyriaque Genet just published a perspective on chiral light and chiral matter interactions in ACS Photonics. In this paper, he shows how chiral optical forces shed new light on chiral light−chiral matter interactions. The key advances selected are representative of the vitality of the current research activity and clearly point toward future designs for all-optical chiral separation strategies of high potential.

The left-handed versus right-handed asymmetry of our living world—a “chirality” seen most often in mirror-image architectures of many biomolecules—is one of its most striking features yet one of the most difficult to comprehend. Immersing chiral molecules within chiral environments is an important route to asymmetry, exploited in chemistry for synthesizing and separating chiral molecules according to their handedness. However, the thermodynamics of such a route is not well understood. In a new publication in Physical Review X, we theoretically explore this thermodynamics using a chiral nanoparticle diffusing within a chiral optical light field.

Demonstrating how chiral degrees of freedom can turn into genuine thermodynamics parameters yields a new and rich playground for further exploring chiral light-matter interactions with far-reaching consequences. To that end, we build a stochastic optomechanical model to reveal and control the mechanisms of asymmetry. One central result of our work is to highlight the thermodynamical significance of the coupling between the chirality of the particle and the chirality of the light field.

Our results pave the way to new opportunities in the context of chiral sensing, recognition, and separation of chiral objects at the nanoscale that should now be implemented experimentally and exploited.

Our perspective about chemistry under vibrational strong coupling just appeared in the Journal of the American Chemical Society. We expose the fundamentals of light-matter strong coupling, the recent advancements in vibro-polaritonic chemistry and the numerous perspectives offered by this new approach, that is easy to implement and thus promising for future exploration of light-matter interactions in molecular and material sciences.